Wgroup member: Xiao Qing Graduate student (2006-2012) Current position: The University of Tokyo; Email: hydrogen_h@163.com

1983. 05 Born in a tranquil small town about 20 miles to the Emei Mountain in Sichuan Province, which is in the southwest of China
Hobbies: Studying History, Enjoying Drama Traveling and Pop Music

Education
2002.9 ~ 2007.7: Expecting B.Sc. Degree in Chemistry, Peking University (in Professor Jianbo Wang’s group)
1998.9 ~ 2002.7: Finished High School Education at Leshan No.1 Senior High School

Honors and Awards
2005.9 The Wusi Scholarship for excellent students in Peking University
2004.9 The Jiali Niangyou Scholarship for excellent students in Peking University

B.Sc thesis: Studies on the Transition Metal-catalyzed Reaction of Alkynes and Diazocarbonyl Compounds
Ph.D thesis: Palladium- or Copper-Catalyzed Cross-Coupling Reactions of p-Toluenesulfonyl Hydrazones

Publications

(1) Investigation on Ru(II)-catalyzed Reaction of [2,3]-Sigmatropic Rearrangement of Sulfur Ylide Generated from Metal Carbene
Qing Xiao and Jianbo Wang
Acta Chim. Sinica 2007, 65, 1733-1735. Click here.

(2) Pd-Catalyzed C=C Double Bond Formation by Coupling of N-Tosylhydrazones with Benzyl Halides
Qing Xiao, Jian Ma, Yang Yang, Yan Zhang and Jianbo Wang
Org. Lett. 2009,11, 4732-4735. Click here. Selected by Synfacts as important paper: Synfacts , 2009, 11, 4732.

(3) Coupling of N-Tosylhydrazones with Terminal Alkynes: Synthesis of Trisubstituted Allenes
Qing Xiao, Ying Xia, Huan Li, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed. 2011, 50, 1114-1117.

(4) CuBr-Catalyzed Coupling of N-Tosylhydra zones and Terminal Alkynes: Synthesis of Benzofurans and Indoles
Lei Zhou, Yi Shi, Qing Xiao, Yizhou Liu, Fei Ye, Yan Zhang and Jianbo Wang
Org. Lett. 2011, 13, 968-971.

(5) Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate
Di Qiu, Zhitong Zheng, Fanyang Mo, Qing Xiao, Yu Tian, Yan Zhang and Jianbo Wang
Org. Lett. 2011, 13, 4988-4991.

(6) Expeditious Synthesis of Phenanthrenes via CuBr2-Catalyzed Coupling of Terminal Alkynes and N-Tosylhydrazones derived from O-Formyl Biphenyls
Fei Ye, Yi Shi, Lei Zhou, Qing Xiao, Yan Zhang, Jianbo Wang
Org. Lett. 2011, 13, 5020-5023.

(7) C(sp)-C(sp3) Bond Formation through Cu-Catalyzed Cross-Coupling of N-Tosylhydrazones and Trialkylsilylethynes
Fei Ye, Xiaoshen Ma, Qing Xiao, Huan Li, Yan Zhang and Jianbo Wang
J. Am. Chem. Soc. 2012, 134, 5742-5745. ( http://dx.doi.org/10.1021/ja3004792).

(8) Rh(II)-Catalyzed Cyclization of Bis-N-tosylhydrazones: An Efficient Approach toward Polycyclic Aromatic Compounds
Ying Xia, Zhenxing Liu, Qing Xiao, Peiyuan Qu, Rui Ge, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed. 2012, 51, 5714-5717.

(9) Transition-Metal-Free Electrophilic Amination of Arylboroxines
Qing Xiao, Leiming Tian, Renchang Tan, Ying Xia, Di Qiu, Yan Zhang and Jianbo Wang
Org. Lett. 2012, 14, 4230-4233.

(10) Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions
Qing Xiao, Yan Zhang, Jianbo Wang
Acc. Chem. Res. 2013, 46, 236-247. (Invited)

(11) Catalyst-Free Intramolecular Formal Carbon Insertion into C-C Bond: a New Approach toward Phenanthrols and Naphthols
Ying Xia, Peiyuan Qu, Zhenxing Liu, Rui Ge, Qing Xiao, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed. 2013, 52, 2543-2546.

(12) Copper-Catalyzed Direct ortho-Alkylation of N-Iminopyridinium Ylides with N-Tosylhydrazones
Qing Xiao, Lin Ling, Fei Ye, Renchang Tan, Leiming Tian, Yan Zhang, Yuxue Li and Jianbo Wang
J. Org. Chem. 2013, 78, 3879-3885. (JOC Most Read Articles in April 2013)

(13) Pd-Catalyzed Three-Component Reaction of Allenes, Aryl Iodides and Diazo Compounds: New Approach to 1,3-Dienes
Qing Xiao, Binglong Wang, Leiming Tian, Yang Yang, Jian Ma, Yan Zhang, Shufeng Chen* and Jianbo Wang*
Angew. Chem. Int. Ed. 2013, 52, 9305-9308.

(14) Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene-Yne-Ketones as Carbene Precursors
Ying Xia, Shuanglin Qu, Qing Xiao, Zhi-Xiang Wang,* Peiyuan Qu, Li Chen, Zhen Liu, Leiming Tian, Zhongxing Huang, Yan Zhang, Jianbo Wang*
J. Am. Chem. Soc. 2013, 135, 13502–13511. (JACS Most Read Articles)

(15) Oxidative Cross-Coupling of Allenyl Ketones and Organoboronic Acids: Expeditious Synthesis of Highly Substituted Furans
Ying Xia, Yamu Xia, Rui Ge, Zhen Liu, Qing Xiao, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed. 2014, 53, 3917-3921.

(16) Pd-Catalyzed Alkyne-Alkyne Cross-Coupling: Access to Conjugated Enynes via Metal Carbene Migratory Insertion
Ying Xia, Zhen Liu, Rui Ge, Qing Xiao, Yan Zhang, Jianbo Wang
Chem. Commun. 2015, 51, 11233-11235.

(17) Palladium-Catalyzed Oxidative Cross-Coupling of Conjugated Enynones with Organoboronic Acids
Ying Xia, Rui Ge, Li Chen, Zhen Liu, Qing Xiao, Yan Zhang, Jianbo Wang
J. Org. Chem. 2015, 80, 7856-7864.

(18) Rh(I)-Catalyzed Coupling of Conjugated Enynones with Arylboronic Acids: Synthesis of Furyl-Containing Triarylmethanes
Ying Xia, Li Chen, Peiyuan Qu, Guojing Ji, Sheng Feng, Qing Xiao, Yan Zhang, Jianbo Wang
J. Org. Chem. 2016, 81, accepted.