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Prof. Jianbo Wang

Dr. Yan Zhang

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Wgroup member: Fanyang Mo

Graduate student (2006.9~2010.7)

Current position: College of Engineering, Peking University;

Email: fmo@pku.edu.cn

1982.03 Born in Liao Yang City of Liao Ning Province, which is a highly industrialized region in the northeast of China.
Hobbies: Football, Badminton, Violin and Piano.

Education
2006.9~present: Expecting Ph. D. in Organic Chemistry, Peking University. Advisor: Professor Jianbo Wang.
2004.9~2006.7: M. Sc., Beijing Institute of Technology. Advisor: Professor Zhiming Zhou.
2000.9~2004.7: B.Sc., Beijing Institute of Technology.
1997.9 ~ 2000.7: No.1 High Middle School of Liao Yang.

Honors and Awards
2003 Xu Teli Scholarship, which is the highest one at BIT.
2004 and 2006 Excellent graduate of Beijing.

Ph.D thesis: Synthetic Application of Diazo Compound in Stereoselective Synthesis and Aromatic C-H / C-N bond Activation and Functionalization

Publications

(1) Highly Diastereoselective Addition of the Lithium Enolate of Alpha-Diazoacetoacetate to N-Sulfinyl Imines: Enantioselective Synthesis of 2-Oxo and 3-Oxo Pyrrolidines
Changqing Dong, Fanyang Mo, and Jianbo Wang
J. Org. Chem. 2008, 73, 1971-1974.Click here.

(2) AuPPh3Cl/AgOTf-Catalyzed Reaction of Terminal Alkynes: Nucleophilic Addition to Activated C=O Bond
Changkun Li, Fanyang Mo, Weibin Li and Jianbo Wang
Tetrahedron Lett. 2009, 6053-6056. Click here.

(3) Direct Conversion of Arylamines to the Pinacol Boronates: A Metal-Free Borylation Process
Fanyang Mo, Yubo Jiang, Di Qiu, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed.
2010, 49, 1846-1849. Click here. Selected by Editors as Hot Paper: Click here.

(4) Gold-Catalyzed Halogenation of Aromatics by N-Halosuccinimides
Fanyang Mo, Jerry Mingtao Yan, Di Qiu, Fei Li, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed.
2010, 49, 2028-2032. Click here.

(5) Enantioselective Synthesis of Condensed and Transannular Ring Skeletons Containing Pyrrolidine Moiety
Fanyang Mo, Fei Li, Di Qiu and Jianbo Wang
Tetrahedron
, 2010, 66, 1274-1279. Click here.

(6) Diastereoselective Addition of Lithium Enolate of gama-Substituted alpha–Diazoacetoacetate to N-Sulfinyl Imines
Fangyang Mo, Fei Li and Jianbo Wang
Chinese Science Bulletin
2010, 55, 2847-2854.

(7) Gold(III)-Catalyzed Halogenation of Aromatic Boronates with N-Halosuccinimides
Di Qiu, Fanyang Mo, Zhitong Zheng, Yan Zhang and Jianbo Wang
Org. Lett. 2010, 12, 5474-5477.

(8) A Base-Free, One-Pot Diazotization/Cross-Coupling of Anilines with Arylboronic Acids
Fanyang Mo, Di Qiu, Yubo Jiang, Yan Zhang and Jianbo Wang
Tetrahedron Lett. 2011, 52, 518-522.

(9) New Developments in Aromatic Halogenation, Borylation and Cyanation
Di Qiu, Fanyang Mo, Zhitong Zheng, Yan Zhang and Jianbo Wang
Chimia 2011, 65, 909-913.

(10) Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate
Di Qiu, Zhitong Zheng, Fanyang Mo, Qing Xiao, Yu Tian, Yan Zhang and Jianbo Wang
Org. Lett. 2011, 13, 4988-4991.

(11) Increments for 1H and 13C NMR Chemical Shifts in Pinacol Arylboronates
Di Qiu, Zhitong Zheng, Fanyang Mo, Yan Zhang and Jianbo Wang
Can. J. Chem. 2012, 90, 71-74.

(12) Progress on the Aromatic C-H Bond Functionalization
Fanyang Mo, Yan Zhang, Jianbo Wang
Journal of Yunnan University of the Nationalities (Natural Sciences Edition), 2011, 20, 317-326. (A review in Chinese)

(13) Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement
Yubo Jiang, Fanyang Mo, Di Qiu, Chunxiang Kuang, Yan Zhang and Jianbo Wang
Chin. J. Chem. 2012, 30, 2297-2302.

(14) Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation
Di Qiu, Liang Jin, Zhitong Zheng, He Meng, Fanyang Mo, Xi Wang, Yan Zhang, and Jianbo Wang
J. Org. Chem. 2013, 78, 1923-1933. (JOC Most-Read Article in November 2012) (For Howard Zimmerman Memorial Issue)

(15) Recent Applications of Arene Diazonium Salts in Organic Synthesis
Fanyang Mo, Guangbin Dong, Yan Zhang and Jianbo Wang
Org. Biomol. Chem. 2013, 11, 1582-2593. (Invited perspective article)

(16) Synthesis of Aryltrimethylstannanes from Arylamines: A Sandmeyer-Type Stannylation Reaction
Di Qiu, He Meng, Liang Jin, Shuai Wang, Shengbo Tang, Xi Wang, Fanyang Mo, Yan Zhang* and Jianbo Wang*
Angew. Chem. Int. Ed. 2013, 52, 11581-11584.

(17) Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group
Xi Wang, Yan Xu, Fanyang Mo, Guojing Ji, Di Qiu, Jiajie Feng, Yuxuan Ye, Songnan Zhang,Yan Zhang and Jianbo Wang
J. Am. Chem. Soc. 2013, 135, 10330-10333. (JACS Most Read Articles in August, 2013)(Highlighted by Synfacts 2013, 9(10), 1113; Highlighted by Angew. Chem.)

(18) Synthesis of Arylboronic Pinacol Esters from Corresponding Arylamines
Di Qiu, He Meng, Liang Jin, Shengbo Tang, Shuai Wang, Fangyang Mo, Yan Zhang and Jianbo Wang (Checked by Austin Smith and Margaret Faul )
Org. Synth. 2014, 91, 106-105.

(19) Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions
Di Qiu, Shuai Wang, Shengbo Tang, He Meng, Liang Jin, Fanyang Mo, Yan Zhang and Jianbo Wang
J. Org. Chem. 2014, 79, 1979-1988. (JOC Most-Read Article)

(20) Synthesis, Structure and Reactivity of Anionic sp2-sp3 Diboron Compounds
Sabrina Pietsch, Emily C. Neeve, David C. Apperley, Rüdiger Bertermann, Fanyang Mo, Di Qiu, Man Sing Cheung, Li Dang, Jianbo Wang, Udo Radius, Zhenyang Lin,* Christian Kleeberg,* and Todd B. Marder*
Chem. Eur. J. 2015, 21, 7082-7099. (Hot Paper)

(21) Rh(I)-Catalyzed C-C Bond Activation of Siloxyvinylcyclopropanes with Diazoesters
Sheng Feng, Fanyang Mo, Ying Xia, Zhenxing Liu, Zhen Liu, Yan Zhang and Jianbo Wang
Angew. Chem. Int. Ed. 2016, 55, 15401-15405 (VIP)(Highlighted by ChemistryViews).

(22) Metal-Free Aromatic Carbon-Phosphorus Bond Formation via a Sandmeyer-Type Reaction
Shuai Wang, Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang
J. Org. Chem. 2016, 81, 11603-11611. (Highlighted by Organic Chemistry Portal)

(23) Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes
Wen-Dao Chu, Lei Zhang, Zhikun Zhang, Qi Zhou, Fanyang Mo, Yan Zhang and Jianbo Wang
J. Am. Chem. Soc. 2016, 138, 14558-14561.

(24) Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions with N-Tosylhydrazones
Di Qiu, Fanyang Mo, Yan Zhang and Jianbo Wang
Adv. Organomet. Chem. 2017, 67, 151-219. (An invited book chapter)

(25) Cu(I)-Catalyzed Asymmetric Cross-Coupling of N-Tosylhydrazones and Trialkylsilylethynes: Enantioselective Construction of C(sp)-C(sp3) Bonds
Wen-Dao Chu, Fangfang Guo, Lefei Yu, Junting Hong, Qianyi Liu, Fanyang Mo, Yan Zhang and Jianbo Wang
Chin. J. Chem. 2018, 36, 217-222.

(26) Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, CF3)
Fanyang Mo,* Di Qiu, Yan Zhang and Jianbo Wang*
Acc. Chem. Res. 2018, 51, 496-506.

 


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?2002 Wgroup, last updated April 12, 2018
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry
Peking University, Beijing 100871, P. R. China

Telephone: 8610-6275-7248 (O); 8610-6275-4777 (Lab) Fax: 8610-6275-1708
Email: wangjb@pku.edu.cn