Wgroup
member: Guojiao Wu
Graduate student (2007.9~2016.7)
1989. 2 Born in Xiaogan, Hubei province. Hobbies: table tennis, badminton
Current position: University of Regensburg (Wangelin group) ;
Email: alkone@yeah.net
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Education
2007.9 ~ 2016.7: College of Chemistry and Molecular
Engineering, Peking University
B.Sc
thesis: Reaction of Diazirine with Arylboronic Acid: A Metal-Free
C-C Bond Forming Process
Ph.D thesis: Transition-Metal-Free Coupling Reactions
of Diazo Compounds and Arylboronic Acids
Publications
(1) Copper-Catalyzed Direct Benzylation or Allylation
of 1,3-Azoles with N-Tosylhydrazones
Xia Zhao, Guojiao Wu, Yan Zhang and Jianbo Wang
J. Am. Chem. Soc. 2011, 133,
3296-3299.
(2) Trifluoromethylthiolation of Diazo Compounds via Copper
Carbene Migratory Insertion
Xi Wang, Yujing Zhou, Guojing Ji, Guojiao Wu, Ming Li, Yan Zhang,
and Jianbo Wang
Eur.
J. Org. Chem.
2014, 3093-3096.
(3) Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation
of Organoboronic Acids with 2,2,2-Trifluorodiazoethane
Guojiao Wu, Yifan Deng, Chaoqiang Wu, Xi Wang, Yan Zhang, and Jianbo
Wang
Eur.
J. Org. Chem.
2014, 4477-4481. (Most-Accessed-Article
in June 2014)
(4) Synthesis of alpha-Aryl Esters and Nitriles via Deaminative Coupling
of alpha-Aminoesters and alpha-Aminoacetonitriles with Arylboronic
Acids
Guojiao Wu, Yifan Deng, Chaoqiang Wu, Yan Zhang, Jianbo Wang
Angew.
Chem. Int. Ed.
2014, 53, 10510-10514. (Angew. Chem.
Most-Accessed Article in August 2014)
(5) Cu(I)-Catalyzed Alkylation of Polyfluoroarenes through Direct
C-H Bond Functionalization
Shuai Xu, Guojiao Wu, Fei Ye, Xi Wang, Huan Li, Xia Zhao, Yan Zhang,
Jianbo Wang
Angew.
Chem. Int. Ed.
2015, 54, 4669-4672.
(6) Cu(I)-Catalyzed Three-Component Coupling of N-Tosylhydrozones,
Alkynes and Azides: Synthesis of Trisubstituted 1,2,3-Triazoles
Zhikun Zhang, Qi Zhou, Fei Ye, Ying Xia, Guojiao Wu, Mohammad Lokman
Hossain, Yan Zhang, and Jianbo Wang
Adv.
Synth. Cat. 2015,
357, 2277-2286. (For
special issue dedicated to Prof. Stephen L. Buchwald)
(7) Cu(I)-Catalyzed Cross-Coupling of Terminal Alkynes with Trifluoro-methyl
Ketone N-Tosylhydrazones: Access to 1,1-Difluoro-1,3-enynes
Zhikun Zhang, Qi Zhou, Weizhi Yu, Tianjiao Li, Guojiao Wu, Yan Zhang,
Jianbo Wang
Org.
Lett.
2015, 17, 2474-2477.
(8) Palladium-Catalyzed Cross-Coupling of Aryl Fluorides with N-Tosylhydrazones
via C-F Bond Activation
Haiqing Luo, Guojiao Wu, Shuai Xu, Kang Wang, Chaoqiang Wu, Yan Zhang,
and Jianbo Wang
Chem.
Commun.
2015, 51, 13321-13323.
(9) Ag(I)-Catalyzed N-Trifluoroethylation
of Anilines and O-Trifluoroethylation of Amides with 2,2,2-Trifluorodiazoethane
Haiqing Luo, Guojiao Wu, Yan Zhang and Jianbo Wang
Angew.
Chem. Int. Ed.
2015, 54, 14503-14507.
(10) Synthesis of Allenylphosphonates through Cu(I)-Catalyzed Coupling
of Terminal Alkynes with Diazophosphonates
Chenggui Wu, Fei Ye, Guojiao Wu, Shuai Xu, Guisheng Deng,* Yan Zhang,
Jianbo Wang*
Synthesis
2016,
48, 751-760.
(11) Metal-Free Oxidative Cross-Coupling of Diazirines with Arylboronic
Acids
Guojiao Wu, Xia Zhao,* Wenzhi Ji, Yan Zhang, and Jianbo Wang*
Chem.
Commun.
2016, 52, 1961-1963. (Highlighted
by Synfacts 2016, 12(3),
0294)
(12) Transition-Metal-Free Cascade Reaction of alpha-Halo-N-tosylhydrazones,
Indoles and Arylboronic Acids
Guojiao Wu, Yifan Deng, Haiqing Luo, Junliang Zhou, Tianjiao Li, Yan
Zhang, and Jianbo Wang
Chem.
Commun.
2016, 52, 5266-5268.
(13) Palladium-Catalyzed Cascade Reaction of alpha-Halo-N-Tosylhydrazones,
Indoles and Aryl Idodies
Guojiao Wu, Yifan Deng, Haiqing Luo, Tianjiao Li, Yan Zhang and Jianbo
Wang
Asian
J. Org. Chem. 2016,
5, 874-877.
(14) One-Carbon Homologation of Arylboronic Acids: A Convenient Approach
to the Synthesis of Pinacol Benzylboronates
Chaoqiang Wu, Guojiao Wu, Yan Zhang and Jianbo Wang
Org.
Chem. Front.
2016, 3, 817-822.
(15) Coupling of Arylboronic Acids with Benzyl
Halides or Mesylates without Adding Transition Metal Catalysts
Guojiao Wu, Shuai Xu, Yifan Deng, Chaoqiang Wu, Xia Zhao, Wenzhi Ji,
Yan Zhang and Jianbo Wang
Tetrahedron
2016,
72, 8022-8030.
(16) Cu(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with
Diazo Esters: Ring-Opening C-C Bond Formations
Hang Zhang, Guojiao Wu, Heng Yi, Tong Sun, Bo Wang, Yan Zhang, Guangbin
Dong, Jianbo Wang
Angew.
Chem. Int. Ed. 2017,
56, 3945-3950.
(17) Catalytic asymmetric trifluoromethylthiolation via enantioselective
[2,3]-sigmatropic rearrangement of sulfonium ylides
Zhikun Zhang, Zhe Sheng, Weizhi Yu, Guojiao Wu, Rui Zhang, Wen-Dao
Chu, Yan Zhang and Jianbo Wang
Nature
Chem. 2017,
9, 970-976
(Highlighted by Science
China: Chemistry; Highlighted by Angew.
Chem. Int. Ed.)
(18) Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and
Benzyl Bromides via Carbene Migratory Insertion
Yunpeng Gao, Guojiao Wu, Qi Zhou and Jianbo Wang
Angew.
Chem. Int. Ed. 2018,
57, 2716-2720.