报告摘要

ATR-FUV spectroscopy for condensed states allows one to explore various researches in physical chemistry, analytical chemistry, nanoscience and technology, materials science, and organic chemistry. In my talk I put particular emphasis on following three major topics: (1) Studies of electronic transitions and structure of a variety of molecules, which one cannot investigate by ordinary UV spectroscopy. The combined use of ATR-FUV spectroscopy and quantum chemical calculations allows to investigate various electronic transitions including σ, n–Rydberg transitions. ATR-FUV spectroscopy may open a new avenue for σ-chemistry. (2) ATR-FUV spectroscopy enables one to measure the first electronic transition of water at around 160 nm without peak saturation. Using this band, one can study electronic structure of water, aqueous solutions, and adsorbed water. (3) ATR–FUV spectroscopy has its own advantages of ATR method as a surface analysis method. ATR-FUV spectroscopy is a powerful method for exploring a variety of top surface phenomena (～50nm) of adsorbed water, polymers, graphene, organic materials, ionic liquids, and so on. As the recent application of ATR-FUV-UV spectroscopy studies on electronic transitions from σ orbitals in various saturated molecules are introduced first, and then applications of ATR-FUV spectroscopy to studies on water, aqueous solutions, and adsorbed water are discussed. Applications of ATR-FUV spectroscopy to other materials researches such as polymers, ionic liquids, inorganic semiconductors, graphene, and carbon nanocomposite follow.

报告人简介

尾崎幸洋教授是国际知名光谱学家，研究涉及远紫外，表面等离子共振、近红外、红外、拉曼光谱、量化计算、二维相关谱及化学计量学等领域，他在Angew. Chem. Int. Ed., Chem. Sci. Chem. Rev., Chem. Soc. Rev等顶级国际学术期刊上发表论文、综述上千篇，论文被引用3,4000篇次，H-指数为85。出版专著17本，他获得获得中华人民共和国政府颁发的友谊奖并得到了李强总理的接见等15项国际奖。在日本获得科学技术最高奖等10项国内奖。